姓名:田仕凯 教授 单位:中国科学技术大学 邮箱:tiansk@ustc.edu.cn |
主要研究方向与成果:
从事有机合成化学研究,主要研究含氮有机物中氨基的活化方法,发展了一系列基于碳 氮键和氮-硫键断裂的新型选择性有机化学反应,简便地构建复杂有机分子,在重要学术刊物上发表100多篇论文。
[1] Xue-Song Wu, Yan Chen, Man-Bo Li, Meng-Guang Zhou, and Shi-Kai Tian*, Direct Substitution of Primary Allylic Amines with Sulfinate Salts, J. Am. Chem. Soc. 2012, 134, 14694-14697.
[2] Man-Bo Li, Yong Wang, and Shi-Kai Tian*, Regioselective and Stereospecific Cross-Coupling of Primary Allylic Amines with Boronic Acids and Boronates through Palladium-Catalyzed C-N Bond Cleavage, Angew. Chem., Int. Ed. 2012, 51, 2968-2971.
[3] Fu-Lai Yang and Shi-Kai Tian*, Iodine-Catalyzed Regioselective Sulfenylation of Indoles with Sulfonyl Hydrazides, Angew. Chem., Int. Ed. 2013, 52, 4929-4932.
[4] Dao-Juan Cheng, Liang Yan, Shi-Kai Tian*, Ming-Yue Wu, Lu-Xin Wang, Zi-Li Fan, Sheng-Cai Zheng, Xin-Yuan Liu*, and Bin Tan*, Highly Enantioselective Kinetic Resolution of Axially Chiral BINAM Derivatives Catalyzed by a Brønsted Acid, Angew. Chem., Int. Ed. 2014, 53, 3684-3687.
[5] Meng-Zeng Zhu, Dong Xie, and Shi-Kai Tian*, Highly Regioselective Aromatic C−H Allylation of N(Arylmethyl)sulfonimides with Allyl Grignard Reagents Involving Benzylic C−N Cleavage, Org. Lett. 2021, 23, 6877-6881.